Sir Ronald Sydney Nyholm was an Australian chemist, born on 29 January 1917 at Broken Hill, New South Wales, Australia, as the fourth in a family of six children. Broken Hill is a mining town whose streets are named after minerals, a fit place for to sire an inorganic chemist. Beryl-and-Sulphide is a road junction. He attended Burke Ward Public School and Broken Hill High School. Nyholm married Maureen Richardson of Epping, a suburb of Sydney, NSW, at St Mary Abbotts Parish Church,[1] Kensington, London on 6 August 1948. Ronald Nyholm’s father, Eric Edward Nyholm (1878–1932) was a railway guard who worked for the Silverton Tramway a railway line that ran from Broken Hill to the South Australian border with NSW; whilst his paternal grandfather, Erik Nyholm (1850–1887) was a coppersmith born in Nykarleby in the Swedish-speaking part of Finland, who migrated to Adelaide in 1873. Ronald Nyholm valued his Finnish roots and was particularly proud in his election in 1959 as Corresponding Member of the Finnish Chemical Society. Nyholm was educated at Broken Hill High School; the University of Sydney (B.Sc., 1938; M.Sc., 1942) and University College, London (Ph.D., 1950, supervised by Sir Christopher Ingold; D.Sc., 1953).[2] On graduation Ron became a High School teacher - a contractual requirement of his scholarship to university. He then joined the Eveready Battery Co as a chemist where he was frustrated that his work to make longer lasting batteries was not well received by the marketing department. He then returned to teaching but now in tertiary education. During World War II he was a Gas Officer as the civil defence forces were very concerned that the likely Japanese invasion would include gas attacks. He was lecturer, then senior lecturer in Chemistry at Sydney Technical College from 1940 to 1951, although on leave in London from 1947. From 1952 to 1954 he was associate professor of Inorganic Chemistry at the New South Wales University of Technology. In 1954 he was elected President of the Royal Society of New South Wales. In 1955, Nyholm returned to England as Professor of Chemistry at University College London, until his death in a motorcar accident on the outskirts of Cambridge, England, 4 December 1971.[3]
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Nyholm's research in inorganic chemistry was primarily concerned with the preparation of transition metal compounds, particularly those involving organo-arsenic ligands. His interest in the organoarsenic chemistry was fostered at the University of Sydney by George Joseph Burrows (1888–1950). Using the strong chelating ligand diars, Nyholm demonstrated a range of oxidation states and coordination numbers for several of the transition metals.[4] Nyholm noted that the term ‘unusual valence state’ had an ‘historical, but not chemical significance.’ ‘The definition of usual oxidation state refers to oxidation states that are stable in environments made up of those chemical species that were common in classical inorganic compounds, e.g. oxides, water and other simple oxygen donors, the halogens, excluding fluorine, and sulphur. Nowadays, however, such species constitute only a minority of the vast number of donor atoms and ligands that can be attached to metal.’
After joining Sydney Technology college in 1940 Ron formed a close personal friendship with Francis (Franky) Dwyer and they collaborated in their research. Despite heavy teaching loads, between 1942 and 1947 they reported complexes of rhodium, iridium and osmium in seventeen papers in the Journal and Proceedings of the Royal Society of New South Wales.[5]
One of Nyholm’s early successes was the preparation of an octahedral complex of trivalent nickel [Ni(diars)2Cl2]Cl, by aerial oxidation of the red salt of bivalent nickel [Ni(diars)2]Cl2.[6] He also described stable complexes of quadrivalent nickel such as the deep blue [Ni(diars)2Cl2][ClO4]2, by nitric acid oxidation of the trivalent complex.[7] This stabilisation of higher oxidation states became significant in the Nyholm-Rail reaction where the ditertiary arsine, diars undergoes a condensation reaction to a tritertiary arsine, triars. Nyholm prepared examples of divalent octahedral complexes of the type M(diars)2X2, where X is Cl, Br or I, and M is …
Cr Mn Fe Co Ni
Mo Tc Ru Pd
W Re Os Pt
Many of these divalent complexes are sensitive to aerial oxidation, the chromium complex especially so, even reducing anaerobic water. Indeed numerous previous attempts to prepare Cr(diars)2X2 had proven unsuccessful. The chromium compounds were eventually synthesized by his co-worker Dr Tony Rail only a month before Nyholm’s death, using rigorously anhydrous and anoxygenous conditions.[8]
Together with Professor Ronald Gillespie, Nyholm developed the VSEPR concept, which emphasized classical pictures of bonding, adapted to include features of quantum theory, but focusing on electron clouds of varying density within a probability envelope.
In 2009 a new mineral was discovered in Broken Hill. Its structure was elucidated by Elliot et al.[9] The mineral was named Nyholmite after Ron Nyholm, in recognition of his Broken Hill roots, and his love of inorganic chemistry. It is of course very fitting that it is an arsenic compound, an element that featured strongly in his research career. It is a cadmium-zinc arsenate species, isostructural with the minerals of the hureaulite group. The mineral occurs in a quartz-garnet-arsenopyrite matrix as white globules, tufted aggregates of fibrous crystals and radiating hemispheres of thin, colourless, bladed crystals.
In his inaugural lecture as professor of chemistry at University College London, Nyholm spoke of his concern for the teaching of chemistry.[10][11] In 1957 Nyholm organized the first of an annual series of Summer Schools at University College on new aspects of chemical knowledge and theory, and demonstrations of new equipment. In the early sixties, the Nuffield Foundation, at least partly as a result of Nyholm’s influence, established the Science Teaching project, of which Nyholm was the first Chairman of the Chemistry Consultative Committee. This led to the development of experiential GCE courses that emphasized the process of chemistry, rather than the recall of chemical facts, and explored the role of chemistry in society. In 1971 Ron published an article entitled 'Education for Change' in which he differentiated between education and training as it applies to chemistry.[12] He defined education as ‘a process in which a person receives a training for a full life in a rapidly changing modern society, carried out in such a manner as will ensure the maximum development of the individual personality'. He was not a person who placed too much emphasis on fact-burdened and fact-tested learning such as in the National Curriculum developments in England in the nineteen-nineties.
Nyholm defined training for a full life as including:
Nyholm was passionately associated with industry all of his life. One of his earliest jobs was as a chemist at Eveready Batteries in Sydney. The application of science to useful products was of great importance to him and he loved the DuPont logo "Better things for better living through chemistry". He was a very active consultant to a number of companies including ICI and Johnson Matthey in the UK and DuPont in the US. In addition to his many close academic friends from his work in the UK and Australia, and also in the US - people like Stanley Kirschener at Wayne State and James V Quagliano at Notre Dame, some of his closest friends were in industry. They included world class leaders in chemical industry research such as Duncan S Davies, General Manager of ICI R&D, Wendell F Jackson of DuPont's Explosives Division, the first person to see Teflon when as a young man it was his job cut open the famous cylinder, Hub (Harold M) Hubbard formerly of DuPont and latterly head of SERI (NREL) the Solar Energy Research Institute a man who felt as comfortable in a lab as in boots in the middle of Kansas, and Robert M Cavanaugh, Director of Research at DuPont's Explosives Division. All of these individuals provided Ron, and received from him, stimulation in both the arts and sciences with a firm foothold on the real world. Perhaps the best comment on Ron's relationship with industry was summarized by Williams [13] who felt that Nyholm was not a real believer in theoretical chemical studies as such. Instead he believed that Ron was an old school empiricist, collecting data.... and then searching for correlations.
The Nyholm Prize for Inorganic Chemistry[14] and the Nyholm Prize for Education,[15] founded by the Chemical Society in 1973, are now awarded biennially by the Royal Society of Chemistry.